First pic is the oily one, 2nd pic is what the other 3 look like.Post a GOOD pic of the old plug. If it's oil then your engine is leaking oil from the valve guides or piston rings in one cylinder.
One tank of e-10 shouldn't do much damage, if you've run a few tanks of it there might be a few possibilities of problems occurring. Can you make the car miss fire under load when it's cold?