Actual Science doesn't support most of the myths people keep repeating
Some points:
http://www.sportsscientists.com/search/label/hyponatremia
So much of what people believe about hydration and electrolyes is simply a rehash of marketing campaings and slogans from the sports drink companies. There are some main players in that industry that practically get laughed off stage whenever they attempt to talk to real scientists at conferences. There simply isn't the science to back up their claims.
don't believe the hype people - you are not going to pass out and shrivel up if you get thirsty. Thirst is the best indicator and it isn't too late. Water is still fine to drink.
I've not used a sports drink for a long, long time since "seeing the light". I eat bananas and bars and drink water - and heaven forbid - I drink very diluted cordial for longer events.
The best prevention of cramping is preparation. The fittest won't cramp. If you have specifically prepared well for an event, you won't cramp - unless the event takes you beyond anything you've done in your preparation.
Weighing yourself before and after to work out "sweat rates" doesn't work. When you exercise you burn stored energy. That energy is stored with accompanying water. Let's say you lose 200 to 300 grams of stored carbohydrate. You will lose around a kilo of water stored with it. Yes you do need to drink, but not equal to your weight lost, and certainly don't use it as a firm guide to how much you should be drinking whilst exercising. I know it's a common practice, but it's just not as good as claimed and doesn't work the way people claim. Sure, use it as a guide, but just be aware that you are not only losing water and all the water you do lose wasn't just floating around bathing your cells.
"Replacing what the sweat takes out" is a perfect argument for drinking your own urine!
As for headaches - perhaps tension in the upper shoulders/neck or issues with helmet. I know that I get more of a head ache after 2 hours of riding than I do after 2 hours of running, yet I drink more when riding (simply because it's convenient).